There are some items of clothing that are openly sexually predatory and over the knee boots are somewhere at the top of the list. You can never tell on which side of the fetish border are they, but you can bet your ass they will act as a turn on. For everybody, including yourself!
It's not the first time items like this crossed over from the sex shop, and this one is just as risque as most of them (though I think they are better than the rubber ones that were in every editorial a few years ago). For this reason it is essential to dress them down. Man jacket, plain shirt, no jewelery... Nothing that would make you look like Pretty woman.
But for the woman who has courage and, most importantly, style to wear them... tip of the hat to you. I like nothing better than a woman with some balls!